stream P264 Wash ... thoroughly after handling. Use only outdoors or in a well-ventilated area. The electrolyte is mainly solution of Lithium chloride (LiCl), and aluminum chloride (AlCl 3) in Thionyl chloride (SOCl 2). Shop a large selection of products and learn more about Thionyl chloride, 99%, Alfa Aesar. %PDF-1.5 %���� 0000008902 00000 n GHS SDS requirements and classification criteria do … * Thionyl Chloride can affect you when breathed in. 0000021119 00000 n ], Water, acids, alkalis, ammonia, chloryl perchlorate Not applicable unless there is exposure to an electrolyte. 0000007494 00000 n Chronic –Overexposure can cause symptoms of non-fibrotic lung injury. Prevention. Violently reacts with water to liberate hydrochloric acid and sulfur dioxide [NFPA 10th ed. Suitable products for Thionyl chloride SOCl 2. H331 Toxic if inhaled. Buy Thionyl Chloride GHS Labels from HCL & clearly identify hazards. [Note: Fumes form when exposed to moist air.] thionyl chloride Thionyl dichloride thionyl dichoride; Thionyl dichloride; Show more chemical information. The mixture of thionyl chloride with ethyl acetate in the presence of zinc or iron metal results in an explosively hazardous mixture. * Breathing Thionyl Chloride can irritate the lungs causing coughing and/or shortness of breath. Decisions that inherently pose a risk of injury or a hazard to human beings or property should not be made on the basis of this information. 0000002717 00000 n Thionyl chloride is sold by various chemical suppliers, but due to its hazards it's generally not available to the amateur chemist. Signs and symtoms of exposure :Eye and mucous membrane irritation. the larynx and bronchi, chemical pneumonitis, and pulmonary edema. Linking to a non-federal website does not constitute an endorsement by CDC or any of its employees of the sponsors or the information and products presented on the website. For this reason, improper handling of the battery could lead to distortion, leakage, overheating, explosion, fire, or generation of irritating/corrosive gases and cause human injury or equipment trouble. 0000001570 00000 n The Saft primary Lithium-Thionyl chloride batteries do not contain toxic materials. Toxic exposure to fumes of Thionyl chloride reacting with water may result in delayed pulmonary response, bronchiolitis Oblitereans(inflammmation of the bronchioles). H314 Causes severe skin burns and eye damage. HAZARD SUMMARY * Thionyl Chloride can affect you when breathed in. Applicable part number: GAP-9419-H THAAD KVB . 0000001311 00000 n Toxic exposure to fumes of Thionyl Chloride reacting with water may result in a delayed pulmonary response (longer than two weeks) of bronchiolitis Obliterans-inflammation of the bronchioles. Application Thionyl chloride may be used in the following processes: • To facilitate the synthesis of indenones from 3-hydroxyindanones via dehydroxylation. Inhalation of sulfuryl chloride or thionyl chloride vapors can result in pulmonary edema. * Exposure to Thionyl Chloride can irritate the nose and throat. 500g. 0000002795 00000 n Shipping Requirements: Lithium metal batteries and cells are subject to the shipping requirements and exceptions under 49 CFR 173.185. Thionyl chloride. 0000002248 00000 n 0000003279 00000 n Do not eat, drink or smoke when using this product. 0000001761 00000 n Please strictly observe safety instructions. 0000017598 00000 n Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 … [Note: Fumes form when exposed to moist air. 0000009613 00000 n Wash face, hands and any exposed skin thoroughly after handling. Solubility in other solvents Thionyl Chloride: Decomposes violently on contact with water. Purification Methods: Crude SOCl2 can be freed from sulfuryl chloride, sulfur monochloride and sulfur dichloride by refluxing it with sulfur and then fractionally distilling twice. Important additional information about respirator selection, Sulfinyl chloride, Sulfur chloride oxide, Sulfurous dichloride, Sulfurous oxychloride, Thionyl dichloride, Colorless to yellow to reddish liquid with a pungent odor like sulfur dioxide. The Centers for Disease Control and Prevention (CDC) cannot attest to the accuracy of a non-federal website. Partition coefficient: n None known -octanol/water Not applicable unless there is exposure to an electrolyte. CDC twenty four seven. 0000000892 00000 n The internal component (thionyl chloride) is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1920.1200. Harmful if swallowed. Since most reactions using SOCl 2 evolve these gases, they should be performed only in well‐ventilated hoods. 0000005773 00000 n * Breathing Thionyl Chloride can irritate the lungs causing 0000008223 00000 n ], inhalation, ingestion, skin and/or eye contact, irritation eyes, skin, mucous membrane; eye, skin burns, Centers for Disease Control and Prevention. 0000002751 00000 n 0000001391 00000 n endstream endobj 25 0 obj<. startxref 0000003355 00000 n Lithium Thionyl Chloride Battery. It is a moderately volatile colourless liquid with an unpleasant acrid odour. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 minutes. Precautionary statement (s) Prevention. 24 0 obj<> endobj May cause respiratory irritation. Sulfinyl chloride, Sulfur chloride oxide, Sulfurous dichloride, Sulfurous oxychloride, Thionyl dichloride Colorless to yellow to reddish liquid with a pungent odor like sulfur dioxide. 0000003034 00000 n [The SOCl2 is converted to SO2 and sulfur chlorides. H314 Causes severe skin burns and eye damage. Lithium-Thionyl Chloride (Li-SOCl2) Battery 1/6 Document Number: RD-ER-201501-001 Issued date: 3 January 2015 EVE Energy Co., Ltd Safety and Reliability Lab MATERIAL SAFETY… Precautionary Statements. 0 Causes gastrointestinal/digestive tract burns. Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. Thionyl chloride is widely used to convert carboxylic acids and alcohols to the corresponding acyl chlorides and alkyl chlorides respectively via an internal nucleophilic substitution. Hazard statement (s) H302 Harmful if swallowed. You will be subject to the destination website's privacy policy when you follow the link. It reacts with water to liberate the toxic gases HCl and SO 2 . UN1836 Thionyl chloride, Hazard class: 8; Labels: 8-Corrosive material. 0000005516 00000 n Thionyl chloride should be stored in glass containers at ambient temperature and protected from moisture. Its sale is regulated in many places. P270 Do not eat, drink or smoke when using this product. 0000006724 00000 n * Thionyl Chloride is a CORROSIVE CHEMICAL and contact can severely irritate and burn the skin and eyes with possible eye damage. It is toxic, reacts with water, and is also listed under the Chemical Weapons Convention as it may be used for the production of chemical weapons. H332 Harmful if inhaled. Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. 13 - DISPOSAL CONSIDERATIONS Dispose in accordance with applicable regulations which vary from country to country. This is a high energy density sealed battery containing (Lithium) and (Thionyl Chloride) materials. Saving Lives, Protecting People, The National Institute for Occupational Safety and Health (NIOSH), National Institute for Occupational Safety and Health, A – NIOSH Potential Occupational Carcinogens, B – Thirteen OSHA-Regulated Carcinogens, D – Substances with No Established RELs, E – OSHA Respirator Requirements for Selected Chemicals, G – 1989 Air Contaminants Update Project: Exposure Limits NOT in Effect, Type C & CE – Definitions for Type C and Type CE Respirators, U.S. Department of Health & Human Services. Thionyl chloride is an inorganic compound with the chemical formula SOCl2. 0000004730 00000 n Chronic: Chronic exposure may cause effects similar to those of acute exposure. xref 5.2 Special hazards arising from the substance or mixture Sulphur oxides, Hydrogen chloride gas Container explosion may occur under fire conditions. <<1b2552d1b1366e49b0bd9b0d50bc0452>]>> Thionyl chloride is an inorganic compound with the chemical formula S O Cl 2.It is a moderately volatile colourless liquid with an unpleasant acrid odour. SUPPLEMENTARY SAFETY AND HEALTH DATA: If the battery is broken or leaked the main hazard is the electrolyte. SECTION 2- HAZARD(S) IDENTIFICATION Classification: The batteries described in this SDS are hermetically sealed articles. trailer Impact Of Population Growth On Environment Pdf, Gas Smoker Bbq, Love Is The Answer Lyrics Patoranking, Korg Ca-1 Chromatic Tuner, Ridley Bikes For Sale Uk, Orthodontic Textbooks Pdf, Characteristics Of Life Insurance, Manufacturing Cyber Attack Examples, Cape Town Plants, Premier Inn Blackpool East, Sample Essays Leadership, Foam Back Vs Cork Back Vinyl Flooring, " />stream P264 Wash ... thoroughly after handling. Use only outdoors or in a well-ventilated area. The electrolyte is mainly solution of Lithium chloride (LiCl), and aluminum chloride (AlCl 3) in Thionyl chloride (SOCl 2). Shop a large selection of products and learn more about Thionyl chloride, 99%, Alfa Aesar. %PDF-1.5 %���� 0000008902 00000 n GHS SDS requirements and classification criteria do … * Thionyl Chloride can affect you when breathed in. 0000021119 00000 n ], Water, acids, alkalis, ammonia, chloryl perchlorate Not applicable unless there is exposure to an electrolyte. 0000007494 00000 n Chronic –Overexposure can cause symptoms of non-fibrotic lung injury. Prevention. Violently reacts with water to liberate hydrochloric acid and sulfur dioxide [NFPA 10th ed. Suitable products for Thionyl chloride SOCl 2. H331 Toxic if inhaled. Buy Thionyl Chloride GHS Labels from HCL & clearly identify hazards. [Note: Fumes form when exposed to moist air.] thionyl chloride Thionyl dichloride thionyl dichoride; Thionyl dichloride; Show more chemical information. The mixture of thionyl chloride with ethyl acetate in the presence of zinc or iron metal results in an explosively hazardous mixture. * Breathing Thionyl Chloride can irritate the lungs causing coughing and/or shortness of breath. Decisions that inherently pose a risk of injury or a hazard to human beings or property should not be made on the basis of this information. 0000002717 00000 n Thionyl chloride is sold by various chemical suppliers, but due to its hazards it's generally not available to the amateur chemist. Signs and symtoms of exposure :Eye and mucous membrane irritation. the larynx and bronchi, chemical pneumonitis, and pulmonary edema. Linking to a non-federal website does not constitute an endorsement by CDC or any of its employees of the sponsors or the information and products presented on the website. For this reason, improper handling of the battery could lead to distortion, leakage, overheating, explosion, fire, or generation of irritating/corrosive gases and cause human injury or equipment trouble. 0000001570 00000 n The Saft primary Lithium-Thionyl chloride batteries do not contain toxic materials. Toxic exposure to fumes of Thionyl chloride reacting with water may result in delayed pulmonary response, bronchiolitis Oblitereans(inflammmation of the bronchioles). H314 Causes severe skin burns and eye damage. HAZARD SUMMARY * Thionyl Chloride can affect you when breathed in. Applicable part number: GAP-9419-H THAAD KVB . 0000001311 00000 n Toxic exposure to fumes of Thionyl Chloride reacting with water may result in a delayed pulmonary response (longer than two weeks) of bronchiolitis Obliterans-inflammation of the bronchioles. Application Thionyl chloride may be used in the following processes: • To facilitate the synthesis of indenones from 3-hydroxyindanones via dehydroxylation. Inhalation of sulfuryl chloride or thionyl chloride vapors can result in pulmonary edema. * Exposure to Thionyl Chloride can irritate the nose and throat. 500g. 0000002795 00000 n Shipping Requirements: Lithium metal batteries and cells are subject to the shipping requirements and exceptions under 49 CFR 173.185. Thionyl chloride. 0000002248 00000 n 0000003279 00000 n Do not eat, drink or smoke when using this product. 0000001761 00000 n Please strictly observe safety instructions. 0000017598 00000 n Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 … [Note: Fumes form when exposed to moist air. 0000009613 00000 n Wash face, hands and any exposed skin thoroughly after handling. Solubility in other solvents Thionyl Chloride: Decomposes violently on contact with water. Purification Methods: Crude SOCl2 can be freed from sulfuryl chloride, sulfur monochloride and sulfur dichloride by refluxing it with sulfur and then fractionally distilling twice. Important additional information about respirator selection, Sulfinyl chloride, Sulfur chloride oxide, Sulfurous dichloride, Sulfurous oxychloride, Thionyl dichloride, Colorless to yellow to reddish liquid with a pungent odor like sulfur dioxide. The Centers for Disease Control and Prevention (CDC) cannot attest to the accuracy of a non-federal website. Partition coefficient: n None known -octanol/water Not applicable unless there is exposure to an electrolyte. CDC twenty four seven. 0000000892 00000 n The internal component (thionyl chloride) is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1920.1200. Harmful if swallowed. Since most reactions using SOCl 2 evolve these gases, they should be performed only in well‐ventilated hoods. 0000005773 00000 n * Breathing Thionyl Chloride can irritate the lungs causing 0000008223 00000 n ], inhalation, ingestion, skin and/or eye contact, irritation eyes, skin, mucous membrane; eye, skin burns, Centers for Disease Control and Prevention. 0000002751 00000 n 0000001391 00000 n endstream endobj 25 0 obj<. startxref 0000003355 00000 n Lithium Thionyl Chloride Battery. It is a moderately volatile colourless liquid with an unpleasant acrid odour. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 minutes. Precautionary statement (s) Prevention. 24 0 obj<> endobj May cause respiratory irritation. Sulfinyl chloride, Sulfur chloride oxide, Sulfurous dichloride, Sulfurous oxychloride, Thionyl dichloride Colorless to yellow to reddish liquid with a pungent odor like sulfur dioxide. 0000003034 00000 n [The SOCl2 is converted to SO2 and sulfur chlorides. H314 Causes severe skin burns and eye damage. Lithium-Thionyl Chloride (Li-SOCl2) Battery 1/6 Document Number: RD-ER-201501-001 Issued date: 3 January 2015 EVE Energy Co., Ltd Safety and Reliability Lab MATERIAL SAFETY… Precautionary Statements. 0 Causes gastrointestinal/digestive tract burns. Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. Thionyl chloride is widely used to convert carboxylic acids and alcohols to the corresponding acyl chlorides and alkyl chlorides respectively via an internal nucleophilic substitution. Hazard statement (s) H302 Harmful if swallowed. You will be subject to the destination website's privacy policy when you follow the link. It reacts with water to liberate the toxic gases HCl and SO 2 . UN1836 Thionyl chloride, Hazard class: 8; Labels: 8-Corrosive material. 0000005516 00000 n Thionyl chloride should be stored in glass containers at ambient temperature and protected from moisture. Its sale is regulated in many places. P270 Do not eat, drink or smoke when using this product. 0000006724 00000 n * Thionyl Chloride is a CORROSIVE CHEMICAL and contact can severely irritate and burn the skin and eyes with possible eye damage. It is toxic, reacts with water, and is also listed under the Chemical Weapons Convention as it may be used for the production of chemical weapons. H332 Harmful if inhaled. Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. 13 - DISPOSAL CONSIDERATIONS Dispose in accordance with applicable regulations which vary from country to country. This is a high energy density sealed battery containing (Lithium) and (Thionyl Chloride) materials. Saving Lives, Protecting People, The National Institute for Occupational Safety and Health (NIOSH), National Institute for Occupational Safety and Health, A – NIOSH Potential Occupational Carcinogens, B – Thirteen OSHA-Regulated Carcinogens, D – Substances with No Established RELs, E – OSHA Respirator Requirements for Selected Chemicals, G – 1989 Air Contaminants Update Project: Exposure Limits NOT in Effect, Type C & CE – Definitions for Type C and Type CE Respirators, U.S. Department of Health & Human Services. Thionyl chloride is an inorganic compound with the chemical formula SOCl2. 0000004730 00000 n Chronic: Chronic exposure may cause effects similar to those of acute exposure. xref 5.2 Special hazards arising from the substance or mixture Sulphur oxides, Hydrogen chloride gas Container explosion may occur under fire conditions. <<1b2552d1b1366e49b0bd9b0d50bc0452>]>> Thionyl chloride is an inorganic compound with the chemical formula S O Cl 2.It is a moderately volatile colourless liquid with an unpleasant acrid odour. SUPPLEMENTARY SAFETY AND HEALTH DATA: If the battery is broken or leaked the main hazard is the electrolyte. SECTION 2- HAZARD(S) IDENTIFICATION Classification: The batteries described in this SDS are hermetically sealed articles. trailer Impact Of Population Growth On Environment Pdf, Gas Smoker Bbq, Love Is The Answer Lyrics Patoranking, Korg Ca-1 Chromatic Tuner, Ridley Bikes For Sale Uk, Orthodontic Textbooks Pdf, Characteristics Of Life Insurance, Manufacturing Cyber Attack Examples, Cape Town Plants, Premier Inn Blackpool East, Sample Essays Leadership, Foam Back Vs Cork Back Vinyl Flooring, " />

thionyl chloride hazards

OSHA HazCom compliant labels are made with chemical & solvent resistant materials. Certain batteries contain small amounts of thionyl chloride, but it's impractical to extract it. Ingestion: Corrosive. 24 29 Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. Thionyl Chloride CAS No 7719-09-7 MATERIAL SAFETY DATA SHEET SDS/MSDS. 1991]. [Note: Reacts violently with water to form sulfur dioxide & hydrogen chloride. Safety hazards have ranged from mild venting of toxic materials to violent explosions and fires. 169 F (76.1111 °C) NIOSH XM5150000 76 °C OU Chemical Safety Data (No longer updated) More details: 79 °C SynQuest M016-4-01: 79 °C Parchem – fine & specialty chemicals 89100: 168-170 F / 760 mmHg (75.5556-76.6667 °C / 760 mmHg) Wikidata Q409171 169 F / 760 mmHg (76.1111 °C / 760 mmHg) Wikidata Q409171 79 °C Sigma-Aldrich SIAL-18438: 75.7 °C / 760 mmHg Kaye & Laby (No longer … Thionyl chlorideRevision Date 14-Feb-2020. Thionyl chloride is listed on schedule 3 of the Chemical Weapons Convention and ordering large amounts may draw attention of the authorities. Hazard statement(s ) H302 Harmful if swallowed. Fires may be fought but only from safe fire fighting distance, evacuate all persons from immediate area of fire. Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. Precautionary statement(s ) P261 Avoid breathing vapours. 0000001174 00000 n 0000010294 00000 n 5.3 Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Thionyl chloride is an inorganic compound with the chemical formula SOCl 2. 0000004033 00000 n Safety considerations of lithium-thionyl chloride cells The use of spirally wound lithium-thionyl chloride (Li-SOCl2) cells is currently limited because of their hazardous behavior. CDC is not responsible for Section 508 compliance (accessibility) on other federal or private website. * Exposure to Thionyl Chloride can irritate the nose and throat. Thionyl chloride is an inorganic acid chloride mainly used as a reagent to prepare carboxylic acid chlorides from carboxylic acids. 0000006028 00000 n 0000005178 00000 n National Institute for Occupational Safety and Health (NIOSH) Recommended Exposure Level TO THIONYL CHLORIDE-air: ceiling concentration 1 ppm: NIOSH* DHHS #92-100,1992: National Occupational Exposure Survey 1983 +T�Ϭzz���[��\�M�It��Gh��|����,Bj��,|8�=��o�j� ��J��TW�SU@2�"���։nl�ZU�YxF���Q*�J�%��Ԓ��d��!�H� ��k��Lת$M�2_��г�U_Z U�@=���,��T��ӥ4��{Xf���ܲ�� PM:�7�#�ҬUQ�z�����" It is a moderately volatile colourless liquid with an unpleasant acrid odour. Because all cells and batteries are defined as “articles”,they are exempt from the requirements of the Hazard Communications Standard. 0000020267 00000 n %%EOF * Thionyl Chloride is a CORROSIVE CHEMICAL and contact can severely irritate and burn the skin and eyes with possible eye damage. 0000000016 00000 n Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. Thionyl chloride solution 2.0 M in methylene chloride; CAS Number: 7719-09-7; Linear Formula: Cl2OS; find Sigma-Aldrich-293121 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich. OSHA Status: The internal component (thionyl chloride) is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1920.1200. Emits dense corrosive fumes in moist air. Binary mixtures of these components seem stable, while ternary mixtures result in spontaneously violent reactions. 12 - ECOLOGICAL INFORMATION When properly used or disposed, the Lithium-Thionyl chloride batteries do not present environmental hazard. Thionyl Chloride: 1.635 Not applicable unless there is exposure to an electrolyte. 27 0 obj<>stream P264 Wash ... thoroughly after handling. Use only outdoors or in a well-ventilated area. The electrolyte is mainly solution of Lithium chloride (LiCl), and aluminum chloride (AlCl 3) in Thionyl chloride (SOCl 2). Shop a large selection of products and learn more about Thionyl chloride, 99%, Alfa Aesar. %PDF-1.5 %���� 0000008902 00000 n GHS SDS requirements and classification criteria do … * Thionyl Chloride can affect you when breathed in. 0000021119 00000 n ], Water, acids, alkalis, ammonia, chloryl perchlorate Not applicable unless there is exposure to an electrolyte. 0000007494 00000 n Chronic –Overexposure can cause symptoms of non-fibrotic lung injury. Prevention. Violently reacts with water to liberate hydrochloric acid and sulfur dioxide [NFPA 10th ed. Suitable products for Thionyl chloride SOCl 2. H331 Toxic if inhaled. Buy Thionyl Chloride GHS Labels from HCL & clearly identify hazards. [Note: Fumes form when exposed to moist air.] thionyl chloride Thionyl dichloride thionyl dichoride; Thionyl dichloride; Show more chemical information. The mixture of thionyl chloride with ethyl acetate in the presence of zinc or iron metal results in an explosively hazardous mixture. * Breathing Thionyl Chloride can irritate the lungs causing coughing and/or shortness of breath. Decisions that inherently pose a risk of injury or a hazard to human beings or property should not be made on the basis of this information. 0000002717 00000 n Thionyl chloride is sold by various chemical suppliers, but due to its hazards it's generally not available to the amateur chemist. Signs and symtoms of exposure :Eye and mucous membrane irritation. the larynx and bronchi, chemical pneumonitis, and pulmonary edema. Linking to a non-federal website does not constitute an endorsement by CDC or any of its employees of the sponsors or the information and products presented on the website. For this reason, improper handling of the battery could lead to distortion, leakage, overheating, explosion, fire, or generation of irritating/corrosive gases and cause human injury or equipment trouble. 0000001570 00000 n The Saft primary Lithium-Thionyl chloride batteries do not contain toxic materials. Toxic exposure to fumes of Thionyl chloride reacting with water may result in delayed pulmonary response, bronchiolitis Oblitereans(inflammmation of the bronchioles). H314 Causes severe skin burns and eye damage. HAZARD SUMMARY * Thionyl Chloride can affect you when breathed in. Applicable part number: GAP-9419-H THAAD KVB . 0000001311 00000 n Toxic exposure to fumes of Thionyl Chloride reacting with water may result in a delayed pulmonary response (longer than two weeks) of bronchiolitis Obliterans-inflammation of the bronchioles. Application Thionyl chloride may be used in the following processes: • To facilitate the synthesis of indenones from 3-hydroxyindanones via dehydroxylation. Inhalation of sulfuryl chloride or thionyl chloride vapors can result in pulmonary edema. * Exposure to Thionyl Chloride can irritate the nose and throat. 500g. 0000002795 00000 n Shipping Requirements: Lithium metal batteries and cells are subject to the shipping requirements and exceptions under 49 CFR 173.185. Thionyl chloride. 0000002248 00000 n 0000003279 00000 n Do not eat, drink or smoke when using this product. 0000001761 00000 n Please strictly observe safety instructions. 0000017598 00000 n Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 … [Note: Fumes form when exposed to moist air. 0000009613 00000 n Wash face, hands and any exposed skin thoroughly after handling. Solubility in other solvents Thionyl Chloride: Decomposes violently on contact with water. Purification Methods: Crude SOCl2 can be freed from sulfuryl chloride, sulfur monochloride and sulfur dichloride by refluxing it with sulfur and then fractionally distilling twice. Important additional information about respirator selection, Sulfinyl chloride, Sulfur chloride oxide, Sulfurous dichloride, Sulfurous oxychloride, Thionyl dichloride, Colorless to yellow to reddish liquid with a pungent odor like sulfur dioxide. The Centers for Disease Control and Prevention (CDC) cannot attest to the accuracy of a non-federal website. Partition coefficient: n None known -octanol/water Not applicable unless there is exposure to an electrolyte. CDC twenty four seven. 0000000892 00000 n The internal component (thionyl chloride) is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1920.1200. Harmful if swallowed. Since most reactions using SOCl 2 evolve these gases, they should be performed only in well‐ventilated hoods. 0000005773 00000 n * Breathing Thionyl Chloride can irritate the lungs causing 0000008223 00000 n ], inhalation, ingestion, skin and/or eye contact, irritation eyes, skin, mucous membrane; eye, skin burns, Centers for Disease Control and Prevention. 0000002751 00000 n 0000001391 00000 n endstream endobj 25 0 obj<. startxref 0000003355 00000 n Lithium Thionyl Chloride Battery. It is a moderately volatile colourless liquid with an unpleasant acrid odour. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 minutes. Precautionary statement (s) Prevention. 24 0 obj<> endobj May cause respiratory irritation. Sulfinyl chloride, Sulfur chloride oxide, Sulfurous dichloride, Sulfurous oxychloride, Thionyl dichloride Colorless to yellow to reddish liquid with a pungent odor like sulfur dioxide. 0000003034 00000 n [The SOCl2 is converted to SO2 and sulfur chlorides. H314 Causes severe skin burns and eye damage. Lithium-Thionyl Chloride (Li-SOCl2) Battery 1/6 Document Number: RD-ER-201501-001 Issued date: 3 January 2015 EVE Energy Co., Ltd Safety and Reliability Lab MATERIAL SAFETY… Precautionary Statements. 0 Causes gastrointestinal/digestive tract burns. Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. Thionyl chloride is widely used to convert carboxylic acids and alcohols to the corresponding acyl chlorides and alkyl chlorides respectively via an internal nucleophilic substitution. Hazard statement (s) H302 Harmful if swallowed. You will be subject to the destination website's privacy policy when you follow the link. It reacts with water to liberate the toxic gases HCl and SO 2 . UN1836 Thionyl chloride, Hazard class: 8; Labels: 8-Corrosive material. 0000005516 00000 n Thionyl chloride should be stored in glass containers at ambient temperature and protected from moisture. Its sale is regulated in many places. P270 Do not eat, drink or smoke when using this product. 0000006724 00000 n * Thionyl Chloride is a CORROSIVE CHEMICAL and contact can severely irritate and burn the skin and eyes with possible eye damage. It is toxic, reacts with water, and is also listed under the Chemical Weapons Convention as it may be used for the production of chemical weapons. H332 Harmful if inhaled. Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. 13 - DISPOSAL CONSIDERATIONS Dispose in accordance with applicable regulations which vary from country to country. This is a high energy density sealed battery containing (Lithium) and (Thionyl Chloride) materials. Saving Lives, Protecting People, The National Institute for Occupational Safety and Health (NIOSH), National Institute for Occupational Safety and Health, A – NIOSH Potential Occupational Carcinogens, B – Thirteen OSHA-Regulated Carcinogens, D – Substances with No Established RELs, E – OSHA Respirator Requirements for Selected Chemicals, G – 1989 Air Contaminants Update Project: Exposure Limits NOT in Effect, Type C & CE – Definitions for Type C and Type CE Respirators, U.S. Department of Health & Human Services. Thionyl chloride is an inorganic compound with the chemical formula SOCl2. 0000004730 00000 n Chronic: Chronic exposure may cause effects similar to those of acute exposure. xref 5.2 Special hazards arising from the substance or mixture Sulphur oxides, Hydrogen chloride gas Container explosion may occur under fire conditions. <<1b2552d1b1366e49b0bd9b0d50bc0452>]>> Thionyl chloride is an inorganic compound with the chemical formula S O Cl 2.It is a moderately volatile colourless liquid with an unpleasant acrid odour. SUPPLEMENTARY SAFETY AND HEALTH DATA: If the battery is broken or leaked the main hazard is the electrolyte. SECTION 2- HAZARD(S) IDENTIFICATION Classification: The batteries described in this SDS are hermetically sealed articles. trailer

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December 9, 2020

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